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Well, you could certainly use a flush from what I see in those pics. The problem could be a head gasket, the indicator being the gas smell in the reservoir. The only thing that would cause that, is combustion gasses getting into the cooling system. Oil and coolant mixing does not necessarily occur, and even when it does, it can be an intake gasket problem. Another possibility is that the coolant was low to start with, if its low, you will get air pockets in the engine which will cause it to overheat. Which would leave the question of where the coolant went, has it been leaking? Last but not least, do the fans run when you idle it? If not, that is probably your issue. Head gasket could also have failed as a result of overheating from another issue.